Daguerreotype was the first publicly available photographic process; it was widely used during the 1840s and 1850s. "Daguerreotype" also refers to an image created through this process.
Invented by Louis Daguerre and introduced worldwide in 1839, the daguerreotype was almost completely superseded by 1860 with new, less expensive processes, such as ambrotype, that yield more readily viewable images. There has been a revival of daguerreotype since the late 20th century by a small number of photographers interested in making artistic use of early photographic processes.
To make the image, a daguerreotypist polished a sheet of silver-plated copper to a mirror finish; treated it with fumes that made its surface light sensitive; exposed it in a camera for as long as was judged to be necessary, which could be as little as a few seconds for brightly sunlit subjects or much longer with less intense lighting; made the resulting latent image on it visible by fuming it with mercury vapor; removed its sensitivity to light by liquid chemical treatment; rinsed and dried it; and then sealed the easily marred result behind glass in a protective enclosure.
The image is on a mirror-like silver surface and will appear either positive or negative, depending on the angle at which it is viewed, how it is lit and whether a light or dark background is being reflected in the metal. The darkest areas of the image are simply bare silver; lighter areas have a microscopically fine light-scattering texture. The surface is very delicate, and even the lightest wiping can permanently scuff it. Some tarnish around the edges is normal.
Several types of antique photographs, most often ambrotypes and tintypes, but sometimes even old prints on paper, are commonly misidentified as daguerreotypes, especially if they are in the small, ornamented cases in which daguerreotypes made in the US and the UK were usually housed. The name "daguerreotype" correctly refers only to one very specific image type and medium, the product of a process that was in wide use only from the early 1840s to the late 1850s.
History
Since the Renaissance era, artists and inventors had searched for a mechanical method of capturing visual scenes. Using the camera obscura, artists would manually trace what they saw, or use the optical image as a basis for solving the problems of perspective and parallax, and deciding color values. The camera obscura's optical reduction of a real scene in three-dimensional space to a flat rendition in two dimensions influenced western art, so that at one point, it was thought that images based on optical geometry (perspective) belonged to a more advanced civilization. Later, with the advent of Modernism, the absence of perspective in oriental art from China, Japan and in Persian miniatures was revalued.
In the early seventeenth century, the Italian physician and chemist Angelo Sala wrote that powdered silver nitrate was blackened by the sun, but did not find any practical application of the phenomenon.
The discovery and commercial availability of the halogens—iodine, bromine and chlorine a few years earlier (iodine was discovered by Courtois in 1811, bromine by Lowig in 1825 and Balard in 1826 independently, and chlorine by Scheele in 1774)—meant that silver photographic processes that rely on the reduction of silver iodide, silver bromide and silver chloride to metallic silver became feasible. The daguerreotype is one of these processes, but was not the first, as Niepce had experimented with paper silver chloride negatives while Wedgwood's experiments were with silver nitrate as were Schultze's stencils of letters. Hippolyte Bayard had been persuaded by Francois Arago to wait before making his paper process public.
Previous discoveries of photosensitive methods and substances—including silver nitrate by Albertus Magnus in the 13th century, a silver and chalk mixture by Johann Heinrich Schulze in 1724, and Joseph Niepce's bitumen-based heliography in 1822 contributed to development of the daguerreotype.
The first reliably documented attempt to capture the image formed in a camera obscura was made by Thomas Wedgwood as early as the 1790s, but according to an 1802 account of his work by Sir Humphry Davy:
The images formed by means of a camera obscura have been found too faint to produce, in any moderate time, an effect upon the nitrate of silver. To copy these images was the first object of Mr. Wedgwood in his researches on the subject, and for this purpose he first used the nitrate of silver, which was mentioned to him by a friend, as a substance very sensible to the influence of light; but all his numerous experiments as to their primary end proved unsuccessful.
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The ambrotype (from Ancient Greek: ἀμβροτός — “immortal”, and τύπος — “impression”) also known as a collodion positive in the UK, is a positive photograph on glass made by a variant of the wet plate collodion process. Like a print on paper, it is viewed by reflected light. Like the daguerreotype, which it replaced, and like the prints produced by a Polaroid camera, each is a unique original that could only be duplicated by using a camera to copy it.
The ambrotype was introduced in the 1850s. During the 1860s it was superseded by the tintype, a similar photograph on thin black-lacquered iron, hard to distinguish from an ambrotype if under glass.
The ambrotype was based on the wet plate collodion process invented by Frederick Scott Archer. Ambrotypes were deliberately underexposed negatives made by that process and optimized for viewing as positives instead. In the US, ambrotypes first came into use in the early 1850s. In 1854, James Ambrose Cutting of Boston took out several patents relating to the process. Although Cutting, the patent holder, had named the process after himself, it appears the term, "ambrotype" itself may have been first coined in the gallery of Marcus Aurelius Root, a well-known daguerreotypist, as documented in the 1864 book The Camera and the Pencil as follows: "After considerable improvements, this process was first introduced, in 1854, into various Daguerrean establishments, in the Eastern and Western States, by Cutting & Rehn. In June of this year, Cutting procured patents for the process, though Langdell had already worked it from the printed formulas.
"The process has since been introduced, as a legitimate business, into the leading establishments of our country. The positive branch of it; i.e. a solar impression upon one glass-plate, which is covered by a second hermetically sealed thereto, is entitled the "Ambrotype," (or the "imperishable picture"), a name devised in my gallery.
Root also states (pp. 373): "Isaac Rehn, formerly a successful daguerreotypist, in company with Cutting, of Boston, perfected and introduced through the United States the "Ambrotype," or the positive on glass." What isn't mentioned in the referenced book is the particular year in which the term "ambrotype" was first used.
Ambrotypes were much less expensive to produce than daguerreotypes, the medium that predominated when they were introduced, and did not have the bright mirror-like metallic surface that could make daguerreotypes troublesome to view and which some people disliked. An ambrotype, however, appeared dull and drab when compared with the brilliance of a well-made and properly viewed daguerreotype.
By the late 1850s, the ambrotype was overtaking the daguerreotype in popularity. By the mid-1860s, the ambrotype itself was being replaced by the tintype, a similar image on a sturdy black-lacquered thin iron sheet, as well as by photographic albumen paper prints made from glass plate collodion negatives.
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A tintype, also known as a melainotype or ferrotype, is a photograph made by creating a direct positive on a thin sheet of metal coated with a dark lacquer or enamel and used as the support for the photographic emulsion. Tintypes enjoyed their widest use during the 1860s and 1870s, but lesser use of the medium persisted into the early 20th century and it has been revived as a novelty and fine art form in the 21st.
Tintype portraits were at first usually made in a formal photographic studio, like daguerreotypes and other early types of photographs, but later they were most commonly made by photographers working in booths or the open air at fairs and carnivals, as well as by itinerant sidewalk photographers. Because the lacquered iron support (there is no actual tin used) was resilient and did not need drying, a tintype could be developed and fixed and handed to the customer only a few minutes after the picture had been taken.
The tintype photograph saw more uses and captured a wider variety of settings and subjects than any other photographic type. It was introduced while the daguerreotype was still popular, though its primary competition would have been the ambrotype.
The tintype saw the Civil War come and go, documenting the individual soldier and horrific battle scenes. It captured scenes from the Wild West, as it was easy to produce by itinerant photographers working out of covered wagons.
It began losing artistic and commercial ground to higher quality albumen prints on paper in the mid-1860s, yet survived for well over another 40 years, living mostly as a carnival novelty.
The tintype's immediate predecessor, the ambrotype, was done by the same process of using a sheet of glass as the support. The glass was either of a dark color or provided with a black backing so that, as with a tintype, the underexposed negative image in the emulsion appeared as a positive. Tintypes were sturdy and did not require mounting in a protective hard case like ambrotypes and daguerreotypes.